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카테고리 레이어
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Synthetic Approaches and Applications of Functional Polymers
김병관,유재범,이경진,이재원
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첨단 고분자과학의 핵심인 기능성 고분자의 합성 원리와 공정, 최첨단 응용 분야를 종합한 전문도서입니다. 본 저서는 전도성 및 광활성 고분자의 분자 설계와 합성 방법, 광물리적 기초 이론에서 시작하여, 화학기상증착법(CVD) 및 개시화학기상증착법(iCVD)을 통한 정밀 박막 제조 기술까지 체계적으로 다룹니다. 특히 π-공액 고분자의 에너지 전환 메커니즘과 고분자 모폴로지 제어 전략을 심도 있게 고찰하며, 광열·열전·광전 소재부터 차세대 바이오메디컬 소자에 이르는 광범위한 응용 사례를 제시합니다. 기초 물리화학 원리와 공학적 기상증착 공정 기술을 유기적으로 연결함으로써 연구자들이 기능성 고분자의 구조-물성-공정-응용 상관관계를 명확히 이해하고 혁신적인 미래 첨단소재 설계 능력을 갖출 수 있도록 돕는 지침서가 될 것입니다.
Part 1. Synthesis of Conductive Polymers: Mechanism and Photothermal and Thermoelectric Applications _ 11
Chapter 1 Background of π-Conjugated Polymers and Conductive Polymers _ 14
1.1. Purpose and Scope _ 14
1.2. Bandgap Engineering and Doping Control _ 16
1.3. Photothermal Effect _ 17
1.4. Thermoelectric Effect _ 19
Chapter 2 Polymerization Methods of Heterocyclic Monomers _ 22
2.1. Heterocyclic Polymerization Methods _ 22
2.2. Transition-Metal Catalyzed Cross-Coupling Polymerizations _ 23
2.3. Chemical Oxidation Polymerization _ 37
2.4. Electrochemical polymerization _ 40
2.5. Vapor-Phase Polymerization _ 42
2.6. Solution Casting Polymerization _ 45
2.7. Solid-State polymerization _ 50
Chapter 3 Applications in Photothermal Materials and Thermoelectric Materials _ 54
3.1. Photothermal Applications _ 54
3.2. Thermoelectric Applications _ 57
References _ 60
Part 2. Organic Photoactive Materials: From Molecular Photophysics to Functional Photonic Systems _ 63
Chapter 1 Fundamentals of Photoactivity in Organic Materials _ 68
1.1. Purpose and Scope of This Chapter _ 68
1.2. Light–Matter Interaction and the Concept of Photoactivity _ 69
1.3. Electronic Structure of Organic Photoactive Materials _ 70
1.4. Excited States and Energy Relaxation Pathways _ 72
1.5. Charge Generation, Transport, and Structure–Property Relationships _ 74
Chapter 2 Photophysics of Organic Photoactive Systems _ 76
2.1. Purpose and Scope of This Chapter _ 76
2.2. Optical Excitation and Exciton Formation _ 77
2.3. Exciton Transport, Localization, and Diffusion _ 79
2.4. Competing Excited-State Relaxation Pathways _ 80
2.5. Environmental Effects and Dynamic Disorder _ 81
Chapter 3 Design Strategies for Photoactive Organic Materials _ 82
3.1. Purpose and Scope of This Chapter _ 82
3.2. Bandgap Engineering and Frontier Orbital Control _ 84
3.3. Excited-State Engineering and Photophysical Pathways _ 86
3.4. Side-Chain Engineering and Solid-State Organization _ 89
Chapter 4 Aggregation, Morphology, and Excited-State Dynamics _ 92
4.1. Purpose and Scope of This Chapter _ 92
4.2. Isolated Molecules: Intrinsic Photophysics in the Dilute Regime _ 94
4.3. Weakly Aggregated States: Emergence of Collective Excited States _ 95
4.4. Strongly Aggregated and Packed States: Morphology-Dominated Photophysics _ 96
4.5. Aggregation as an Active Photophysical Control Parameter _ 102
Chapter 5 Photoactive Organic Materials for Optoelectronic Functions _ 104
5.1. Purpose and Scope of This Chapter _ 104
5.2. Organic Photovoltaics: Light Harvesting to Charge Collection _ 105
5.3. Organic Photodetectors: Sensitivity, Speed, and Spectral Selectivity _ 107
5.4. Organic Light-Emitting Devices: From Excitons to Photons _ 108
5.5. Emerging Optoelectronic and Photonic Applications _ 110
References _ 120
Part 3. CVD polymer: Functional Polymeric Thin Films from Parylene Derivatives and their Applications _ 123
Chapter 1 Fundamentals of CVD polymers and Parylene _ 126
1.1. Importance of polymeric thin films in modern engineering _ 126
1.2. Advantages of CVD polymeric thin films and parylene _ 127
1.3. Parylene-Based Polymers _ 129
Chapter 2 Basic processing for CVD of parylene _ 136
2.1. Basic Equipment _ 136
2.2. Deposition kinetics for polymerization via Gorham method _ 140
Chapter 3 Material properties of diverse parylene films (including commercial and synthesized dimers) and corresponding applications _ 146
3.1. Properties of commercialized parylene (N, C, D) _ 146
3.2. Properties of functionalized parylene _ 150
3.3. Simple introduction for application of functionalized parylene _ 153
References _ 157
Part 4. Initiated Chemical Vapor Deposition: Mechanism and Applications _ 159
Chapter 1 Fundamentals of iCVD _ 162
1.1. Purpose and Scope _ 162
1.2. Polymerization mechanism in iCVD _ 163
1.3. Reactor Design and Configuration _ 166
Chapter 2 Material Library and Polymer Design Strategy _ 169
2.1. Purpose and Scope _ 169
2.2. Monomer Library and Chemical Versatility _ 170
2.3. Multi-vinyl monomers and crosslinking _ 172
2.4. Organic-inorganic hybrid polymer films _ 175
Chapter 3 Applications in Biomaterials and Biomedical Devices _ 178
3.1. Purpose and Scope _ 178
3.2. Surface Engineering Principles for Biomaterial and Biomedical Applications _ 179
3.3. Control of Protein Adsorption and Bioactivity _ 180
3.4. Cell and Tissue Culture Systems _ 182
3.5. Biosensor, Diagnostic Devices, and Microfluidics _ 184
References _ 186
Chapter 1 Background of π-Conjugated Polymers and Conductive Polymers _ 14
1.1. Purpose and Scope _ 14
1.2. Bandgap Engineering and Doping Control _ 16
1.3. Photothermal Effect _ 17
1.4. Thermoelectric Effect _ 19
Chapter 2 Polymerization Methods of Heterocyclic Monomers _ 22
2.1. Heterocyclic Polymerization Methods _ 22
2.2. Transition-Metal Catalyzed Cross-Coupling Polymerizations _ 23
2.3. Chemical Oxidation Polymerization _ 37
2.4. Electrochemical polymerization _ 40
2.5. Vapor-Phase Polymerization _ 42
2.6. Solution Casting Polymerization _ 45
2.7. Solid-State polymerization _ 50
Chapter 3 Applications in Photothermal Materials and Thermoelectric Materials _ 54
3.1. Photothermal Applications _ 54
3.2. Thermoelectric Applications _ 57
References _ 60
Part 2. Organic Photoactive Materials: From Molecular Photophysics to Functional Photonic Systems _ 63
Chapter 1 Fundamentals of Photoactivity in Organic Materials _ 68
1.1. Purpose and Scope of This Chapter _ 68
1.2. Light–Matter Interaction and the Concept of Photoactivity _ 69
1.3. Electronic Structure of Organic Photoactive Materials _ 70
1.4. Excited States and Energy Relaxation Pathways _ 72
1.5. Charge Generation, Transport, and Structure–Property Relationships _ 74
Chapter 2 Photophysics of Organic Photoactive Systems _ 76
2.1. Purpose and Scope of This Chapter _ 76
2.2. Optical Excitation and Exciton Formation _ 77
2.3. Exciton Transport, Localization, and Diffusion _ 79
2.4. Competing Excited-State Relaxation Pathways _ 80
2.5. Environmental Effects and Dynamic Disorder _ 81
Chapter 3 Design Strategies for Photoactive Organic Materials _ 82
3.1. Purpose and Scope of This Chapter _ 82
3.2. Bandgap Engineering and Frontier Orbital Control _ 84
3.3. Excited-State Engineering and Photophysical Pathways _ 86
3.4. Side-Chain Engineering and Solid-State Organization _ 89
Chapter 4 Aggregation, Morphology, and Excited-State Dynamics _ 92
4.1. Purpose and Scope of This Chapter _ 92
4.2. Isolated Molecules: Intrinsic Photophysics in the Dilute Regime _ 94
4.3. Weakly Aggregated States: Emergence of Collective Excited States _ 95
4.4. Strongly Aggregated and Packed States: Morphology-Dominated Photophysics _ 96
4.5. Aggregation as an Active Photophysical Control Parameter _ 102
Chapter 5 Photoactive Organic Materials for Optoelectronic Functions _ 104
5.1. Purpose and Scope of This Chapter _ 104
5.2. Organic Photovoltaics: Light Harvesting to Charge Collection _ 105
5.3. Organic Photodetectors: Sensitivity, Speed, and Spectral Selectivity _ 107
5.4. Organic Light-Emitting Devices: From Excitons to Photons _ 108
5.5. Emerging Optoelectronic and Photonic Applications _ 110
References _ 120
Part 3. CVD polymer: Functional Polymeric Thin Films from Parylene Derivatives and their Applications _ 123
Chapter 1 Fundamentals of CVD polymers and Parylene _ 126
1.1. Importance of polymeric thin films in modern engineering _ 126
1.2. Advantages of CVD polymeric thin films and parylene _ 127
1.3. Parylene-Based Polymers _ 129
Chapter 2 Basic processing for CVD of parylene _ 136
2.1. Basic Equipment _ 136
2.2. Deposition kinetics for polymerization via Gorham method _ 140
Chapter 3 Material properties of diverse parylene films (including commercial and synthesized dimers) and corresponding applications _ 146
3.1. Properties of commercialized parylene (N, C, D) _ 146
3.2. Properties of functionalized parylene _ 150
3.3. Simple introduction for application of functionalized parylene _ 153
References _ 157
Part 4. Initiated Chemical Vapor Deposition: Mechanism and Applications _ 159
Chapter 1 Fundamentals of iCVD _ 162
1.1. Purpose and Scope _ 162
1.2. Polymerization mechanism in iCVD _ 163
1.3. Reactor Design and Configuration _ 166
Chapter 2 Material Library and Polymer Design Strategy _ 169
2.1. Purpose and Scope _ 169
2.2. Monomer Library and Chemical Versatility _ 170
2.3. Multi-vinyl monomers and crosslinking _ 172
2.4. Organic-inorganic hybrid polymer films _ 175
Chapter 3 Applications in Biomaterials and Biomedical Devices _ 178
3.1. Purpose and Scope _ 178
3.2. Surface Engineering Principles for Biomaterial and Biomedical Applications _ 179
3.3. Control of Protein Adsorption and Bioactivity _ 180
3.4. Cell and Tissue Culture Systems _ 182
3.5. Biosensor, Diagnostic Devices, and Microfluidics _ 184
References _ 186
저자(글) : 김병관,유재범,이경진,이재원
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상품 정보
저자
김병관,유재범,이경진,이재원
출간일
2026-02-25
ISBN
9791165033385
형식/용량
PDF / 8.55MB
카테고리 분류
대학교재 > 과학/공학계열
대학교재 > 충남대
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